Journal of Organometallic Chemistry p. C31 - C34 (1983)
Update date:2022-09-26
Topics:
Bennett, Martin A.
Rokicki, Andrzej
The 1-cyclohexenylmethoxycarbonyl complex Pt(CO2Me)(C6H9)(dppp) (dppp = 1,3-bis(diphenylphosphino)propane, Ph2PCH2CH2CH2PPh2) undergoes irreversible insertion of CO into the Pt-C6H9 bond under ambient conditions to give Pt(CO2Me)(COC6H9)(dppp), which may contain a dihapto-acyl group; the analogous 1-cyclohexenyl complexes containing 1,2-bis(diphenylphosphino)ethane and cis-1,2-bis(diphenylphosphino)ethylene are unreactive under the same conditions.
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