Intramolecular Diels-Alder Cyclization of Conjugated Aldehydes. Synthesis of a Chlorothricolide Intermediate

DOI: 10.1021/jo00200a062

Source and publish data:

Journal of Organic Chemistry p. 5277 - 5279 (1984)

Update date:2022-07-29

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Authors:

Marshall, James A.

Audia, James E.

Grote, Jonathan

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Article abstract of DOI:10.1021/jo00200a062

Various substituted 2,8,10-undecatrienals have been found to undergo facile intramolecular Diels-Alder cyclization in the presence of dialkylaluminium chlorides to give bicyclo<4.4.0>octahydronaphthalenecarboxaldehydes with high endo selectivity.The metho

Full text of DOI:10.1021/jo00200a062

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