Organic and Biomolecular Chemistry p. 6122 - 6126 (2019)
Update date:2022-08-03
Topics:
Ahmad, Tanveer
Li, Qi
Qiu, Sheng-Qi
Xu, Jian-Lin
Xu, Yun-He
Loh, Teck-Peng
A copper-catalyzed regioselective 1,4-and 1,6-conjugate addition of a silyl reagent to diendioates was established. Various 1,4-and 1,6-protosilylation products were obtained in good yields and with high regioselectivity via tuning the ligands used in the reactions. This protocol has provided a simple and efficient method for the synthesis of multisubstituted functionalized allylsilanes.
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