Reactions of Alkylidenecarbenes Derived from N,N-Disubstituted-2-oxopropanamides: The Formation of 3-Pyrrol-2-ones and 2-Butynamides

DOI: 10.1021/jo00369a019

Source and publish data:

Journal of Organic Chemistry p. 3656 - 3663 (1986)

Update date:2022-09-26

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Authors:

Gilbert, John C.

Blackburn, Brent K.

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Article abstract of DOI:10.1021/jo00369a019

Activation of C-H bonds toward insertion by an alkylidenecarbene was examined in the reaction of N,N-disubstituted-2-oxopropanamides with diethyl (diazomethyl)phosphonate under basic reaction conditions.The intermediate alkylidenecarbene expected to be fo

Full text of DOI:10.1021/jo00369a019

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