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Synthesis of δ-(L-α-Aminoadipyl)-L-cysteinyl-D-valine and δ-(L-α-Aminoadipyl)-L-cysteinyl-D-valylglycine

DOI: 10.1039/P19830000941

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 941 - 944 (1983)

Update date:2022-08-05

Topics: Synthesis   Amino acids   Reactants   Dipeptide   Tripeptide  

Authors:

Thomson, Gordon A.Thomson, Gordon A.

Scott, A. IanScott, A. Ian

Baxter, Robert L.Baxter, Robert L.

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Article abstract of DOI:10.1039/P19830000941

An efficient synthesis of δ-(L-α-aminoadipyl)-L-cysteinyl-D-valine (ACV; 1) and δ-(L-α-aminoadipyl)-L-cysteinyl-D-valylglycine (ACVG; 2) via the protected tripeptide N-benzyloxycarbonyl-1-(p-nitrobenzyl)-δ-(L-α-aminoadipyl)-S-benzyl-L-cysteinyl-D-valine,

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Product name:(S)-2-Amino-5-[(R)-2-[(R)-2-(5-amino-5-carboxy-pentanoylamino)-2-((R)-1-carboxy-2-methyl-propylcarbamoyl)-ethyldisulfanyl]-1-((R)-1-carboxy-2-methyl-propylcarbamoyl)-ethylcarbamoyl]-pentanoic acid

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