Cyclometalation of 2-vinylpyridine with MCl2(PPh 3)3 and MHCl(PPh3)3 (M = Ru, Os)

DOI: 10.1021/om0611305

Source and publish data:

Organometallics p. 2849 - 2860 (2007)

Update date:2022-08-03

Topics:

Authors:

Zhang, Li

Dang, Li

Wen, Ting Bin

Sung, Herman H.-Y.

Williams, Ian D.

Lin, Zhenyang

Jia, Guochen

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Article abstract of DOI:10.1021/om0611305

Treatment of RuCl₃(PPh₃)₃ in benzene at room temperature with 2-vinylpyridine produces the vinylpyridine complex RuCl₂(2-CH₂=CHC₅H₄N)(PPh ₃)₃. In the presen

Full text of DOI:10.1021/om0611305

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Product name:[Os(CHCHC₅H₄N)(CH₂CHC₅H₄N)(P(C₆H₅)3)2]⁽¹⁺⁾*BF₄^(1-)=[Os(CHCHC₅H₄N)(CH₂CHC₅H₄N)(P(C₆H₅)3)2]BF₄

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