A NOVEL AND CONVENIENT REGIO-CONTROLLED SYNTHESIS OF α-HALOGEN-SUBSTITUTED ALLYLSILANES. STEREOSELECTIVE SYNTHESIS OF Z-ALKENYL HALIDES

DOI: 10.1246/cl.1984.1385

Source and publish data:

Chemistry Letters p. 1385 - 1388 (1984)

Update date:2022-08-05

Topics:

Authors:

Hosomi, Akira

Ando, Masatomo

Sakurai, Hideki

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Article abstract of DOI:10.1246/cl.1984.1385

α-Halogen-substituted allylsilanes, prepared conveniently by the in situ reaction of lithiated allyl halides with chlorosilane in a regio-controlled manner, react with various electrophiles to give the corresponding alkenyl halides with high Z preference.

Full text of DOI:10.1246/cl.1984.1385

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