Chemistry Letters p. 1603 - 1606 (1984)
Update date:2022-07-29
Topics: Chiral Catalyst Ligand Hydrogenation Derivatives Stereochemistry Reduction Enantioselectivity Enantiomers coordination complex Asymmetric Hydrogenation Substrate Chiral Induction Carbonyl Compounds Homogeneous Catalysis Rhodium-Catalyzed Bidentate Phosphine Optical activity
Yamamoto, Keiji
Saeed-Ur-Rehman
Conversion has been achieved of two representative chiral diphosphines, (-)-DIOP and (S,S)-Chiraphos, into the corresponding bis(dicyclohexylphosphino)alkane derivatives, the latter being used for chiral ligands of the rhodium(I) catalyst in the homogeneous hydrogenation of prochiral carbonyl compounds.
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