HYDROMETALLATION OF 1-ALKYL-3-TRIFLUOROMETHYL PROPARGYL ALCOHOLS

DOI: 10.1016/S0040-4039(01)81509-4

Source and publish data:

Tetrahedron Letters p. 4749 - 4752 (1984)

Update date:2022-08-05

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Authors:

Hanzawa, Yuji

Kawagoe, Kei-ichi

Tanahasi, Naomi

Kobayashi, Yoshiro

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Article abstract of DOI:10.1016/S0040-4039(01)81509-4

The hydrometallation of trifluormethylated propargyl alcohol derivatives with metal hydride reagents proceeds smoothly to give cis-and trans-olefins on H2O quenching.The halodemetallation of intermediate formed in the reaction process was also examined.

Full text of DOI:10.1016/S0040-4039(01)81509-4

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