REACTIONS OF CIS-DI-ISOCYANIDEBIS(PERFLUOROPHENYL)GOLD(III) COMPLEXES WITH HYDRAZINES. CRYSTAL AND MOLECULAR STRUCTURE OF CIS-(C6F5)2>

DOI: 10.1039/DT9840002035

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2035 - 2038 (1984)

Update date:2022-08-05

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Authors:

Uson, Rafael

Laguna, Antonio

Villacampa, M. Dolores

Jones, Peter G.

Sheldrick, George M.

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Article abstract of DOI:10.1039/DT9840002035

Addition of CNR (R = Ph or p-tolyl) to solutions of cis-ClO4 leads to cis-ClO4, which reacts (a) with NHPhNHPh to give the cationic complexes <<*>(C6F5)2>ClO4, which readily undergo deprotonation to form <<*>(C6F5)2>, and (b) with NH2NHR' (R' H or Ph) to give <<*>(C6F5)2>.The structure of <<*>(C6F5)2> has been determined by X-ray diffraction 1/c, with a = 12.230(2), b = 20.276(3), c = 13.123(2) Angstroem, β = 101.21(2)deg, R = 0.036 for 5 822 reflections>.

Full text of DOI:10.1039/DT9840002035

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