Journal of the American Chemical Society p. 2316 - 2319 (1985)
Update date:2022-08-05
Topics:
Alberti, Angelo
Degl'Innocenti, Alessandro
Pedulli, Gian Franco
Ricci, Alfredo
Radicals of general structure Ar(R3Si)C.-OP(O)Ph2 have been observed by ESR upon reaction of aroylsilanes, Ar(R3Si)CO, with tetraphenylbiphosphine under UV irradiation.The same radicals could in fact be obtained in the reaction of aroylsilanes with diphenylphosphine oxide and di-tert-butyl peroxide (DBP).Addition of OP.(OEt)2 to the carbonyl oxygen was also obsrved when photolyzing mixtures of aroylsilanes, dietyl phosphite, and DBP.In contrast, the photochemical reaction of the same silanes with tetraethyl pyrophosphite led to the detection of radicals, Ar<(EtO)2(O)P>C.-OSSiR3, having the phosphonyl substituent α to the carbon radical center and the silyl group linked to the oxygen atom.Two possible mechanisms which may account for the formation of the observed species, one involving fragmentation of the aroyl-silicon bond and the other the intermediation of a siloxy carbene, aer discussed, an experimental evidence is reported in favour of the former one.
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