Reactions of Diene-conjugated 1,3-Dipolar Intermediates: the Formation of Cyclopropisoquinolines from Benzonitrile o-Alkenylbenzyl Ylides and their Rearrangements to 2-Benzazepines

DOI: 10.1039/c39840001531

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Journal of the Chemical Society. Chemical communications p. 1531 - 1533 (1984)

Update date:2022-08-05

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Authors:

Motion, Keith R.

Robertson, Ian R.

Sharp, John T.

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Article abstract of DOI:10.1039/c39840001531

The α,β:γ,δ-unsaturated nitrile ylides (9), when generated by the 1,3-dehydrochlorination of the benzimidoyl chlorides (8) at room temperature, react by a stereospecific 1,1-cycloaddition to give the cyclopropisoquinolines (10); the latter undergo two

Full text of DOI:10.1039/c39840001531

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