Cationic Platinum Hydride Clusters: X-Ray Crystal Structures of 4H2(PBut3)4>4>24>2 and 4H7(PBut3)4>4>

DOI: 10.1039/c39840001604

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1604 - 1606 (1984)

Update date:2022-08-05

Topics:

Authors:

Goodfellow, Robin J.

Hamon, Elaine M.

Howard, Judith A. K.

Spencer, John L.

Turner, David G.

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Article abstract of DOI:10.1039/c39840001604

Reaction of with strong acid affords the cationic hydrido clusters ²⁺ and ¹⁺, both of which react rapidly with H2 to give the heptahydrido cluster ⁺ shown by X-ray crystallography to have a 'butterfly' core of platinum atoms.

Full text of DOI:10.1039/c39840001604

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