Photoresponsive Crown Ethers. 13. Synthesis of Photoresponsive NS2O Crown Ethers and Application of the Cu(I) Complexes to O2-Binding

Article abstract of DOI:10.1246/bcsj.57.2879

Photoresponsive crown ethers with heavy metal affinity were synthesized: They are the NS₂O crowns bound to photofunctional azobenzene at 4,4'-positions via X(CH₂ or CO) (1(X=CH₂) and 1(X CO), respectively).They efficiently