Journal of Organic Chemistry p. 1353 - 1356 (1988)
Update date:2022-09-26
Topics:
Brady, William T.
Gu, Yi-Qi
The conversion of 2-(carboxyalkoxy)benzils to the corresponding phenoxyketenes to an intramolecular <2+2> ketene cycloaddition to ultimately yield isoflavones and/or 3-aroylbenzofurans.The ketenes may be generated by the classical dehydrochlorination of the acid chloride or by using Perkin reaction conditions, sodium acetate in refluxing acetic anhydride.The initial cycloaddition products are the corresponding β-lactones, which may decarboxylate to the isolated isoflavones and/or 2-aroylbenzofurans.The product distributions are dependent upon the substitution pattern in the orginal benzil acids.
View MoreJinan Jianfeng Chemical Co., Ltd
Contact:0086-531-88110457
Address:sales01(-a-t-)pharmachemm{dot}c+o+m
Jinan Jianfeng Chemical Co., Ltd
Contact:0086-531-88110457
Address:sales01(-a-t-)pharmachemm{dot}c+o+m
SHIFANG SUHONG CHEMICAL CO.,LTD
Contact:+86-838-2224563
Address:Room 1207 Zongchen Sunshine No.128 Taishan South Road,Deyang City,Sichuan China
Dalian Join King Biochemical Tech. Co., Ltd.
Contact:0411 39216206
Address:814 First State Blvd
Beijing Wisdom Chemicals Co., Ltd.
Contact:+86-10-52350335
Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China
Doi:10.1002/1521-4184(200109)334:8/9<263::AID-ARDP263>3.0.CO;2-N
(2001)Doi:10.1002/macp.1976.021770317
(1976)Doi:10.1021/ja01097a037
(1953)Doi:10.1016/S0040-4020(03)00903-7
(2003)Doi:10.1007/BF00742459
()Doi:10.1016/S0040-4039(03)01383-2
(2003)