STEREOISOMERS OF PERHYDROPHENANTHRENE. THE SYNTHESIS AND CRYSTAL STRUCTURE OF A DERIVATIVE OF THE trans-syn-trans ISOMER

DOI: 10.1016/S0040-4020(01)91495-4

Source and publish data:

Tetrahedron p. 3449 - 3454 (1984)

Update date:2022-08-04

Topics:

Authors:

Allinger, Norman L.

Hoenig, Helmut

Burkert, Ulrich

Asolnai, Laszlo

Huttner, Gottfried

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Article abstract of DOI:10.1016/S0040-4020(01)91495-4

The trans-syn-trans isomer of perhydrophenanthrene has the central ring in a boat conformation.A crystalline derivative (the dibenzoate of the cis 9,10-diol) was prepared, and the crystal structure was determined.The boat conformation is slightly twisted, as predicted by molecular mechanics.

Full text of DOI:10.1016/S0040-4020(01)91495-4

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