SPONTANEOUS REACTIONS OF POTASSIUM PHENOXIDE WITH DIBROMOPERFLUOROALKANES. FIRST EVIDENCE FOR BROMOPHILIC ATTACK ON C-Br BONDS BY THE PHENOXIDE ION.

DOI: 10.1016/S0040-4039(01)91263-8

Source and publish data:

Tetrahedron Letters p. 4937 - 4940 (1984)

Update date:2022-07-30

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Authors:

Xingya, Li

Heqi, Pan

Xikui, Jiang

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Article abstract of DOI:10.1016/S0040-4039(01)91263-8

In contrast to earlier reports, It has been found that dibromoperfluoroalkanes actually can react spontaneously with PhOK, yielding fluoroalkyl phenyl ethers as products.Evidence for an anionic chain mechanism involving a bromophilic attack by the phenoxyde ion is presented.

Full text of DOI:10.1016/S0040-4039(01)91263-8

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