Journal of Fluorine Chemistry p. 349 - 354 (1985)
Update date:2022-08-05
Topics:
Hudlicky, Milos
Ethyl 2-chloro-1,1,2-trifluoroethyl ether heated with boron trifluoride etherate gave ethyl fluoride and chlorofluoroacetyl fluoride.When heated with aluminium chloride, it afforded a mixture of ethyl fluoride, ethyl chloride, chlorofluoroacetyl fluoride, and chlorofluoroacetyl chloride.Treatment of the acyl halides with ethanol yielded ethyl chlorofluoroacetate.Butyl and octyl 2-chloro-1,1,2-trifluoroethyl ethers gave directly butyl and octyl chlorofluoroacetates, respectively, under similar conditions.
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(1985)Doi:10.1016/S0040-4039(00)61871-3
(1985)Doi:10.1039/c0dt00902d
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