A New Route to (-)-Cherylline via a Regiocontrolled Polonovski-type Reaction as the Key Step

DOI: 10.1039/c39840001646

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Journal of the Chemical Society. Chemical communications p. 1646 - 1647 (1984)

Update date:2022-08-04

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Authors:

Nomoto, Takashi

Nasui, Nobuyuki

Takayama, Hiroaki

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Article abstract of DOI:10.1039/c39840001646

A facile and efficient synthesis of (-)-cherylline (1) was accomplished in 46percent overall yield starting from the readily accessible (12S)-(-)-3,9-dibenzoyloxy-2-methoxy-tetrahydro-6,12-methanodibenzazocine (4) via a regiocontrolled Polonovski-typ

Full text of DOI:10.1039/c39840001646

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