Real-time kinetic study of the reaction F + NO2

Article abstract of DOI:10.1063/1.444668

The title reaction was studied in real time by observing infrared fluorescence resulting from the competitive reaction F + H2.With N2 as a collision partner, the limiting rate constants were found to be k₀ = 9.8+/-1.6x10^-31 cm⁶ molecule^-2 s^-1 and k_infinite = 3.2+/-0.8x10^-11 cm³ molecule^-1 s^-1, as determined by fitting the experimental data to Kassel, and modified Lindemann-Hinshelwood models.Measurements with argon showed it to be slightly less effective as stabilizing the reaction complex.Calculations indicate that both FNO2 and FONO are formed in the reaction, with a product ratio of FONO/FNO2 ca. 7.

Full text of DOI:10.1063/1.444668

Realtime kinetic study of the reaction F+NO2
D. M. Fasano and N. S. Nogar
Citation: The Journal of Chemical Physics 78, 6688 (1983); doi: 10.1063/1.444668
View online: http://dx.doi.org/10.1063/1.444668
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/78/11?ver=pdfcov
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93.180.53.211 On: Thu, 13 Feb 2014 09:27:05

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
93.180.53.211 On: Thu, 13 Feb 2014 09:27:05

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
93.180.53.211 On: Thu, 13 Feb 2014 09:27:05

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
93.180.53.211 On: Thu, 13 Feb 2014 09:27:05

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
93.180.53.211 On: Thu, 13 Feb 2014 09:27:05

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
93.180.53.211 On: Thu, 13 Feb 2014 09:27:05

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
93.180.53.211 On: Thu, 13 Feb 2014 09:27:05