NOUVELLE METHODE DE PREPARATION DE CETONES, ESTER ET NITRILE BENZYLIQUES α-FLUORES OU α,α-DIFLUORES

DOI: 10.1016/S0040-4039(00)96124-0

Source and publish data:

Tetrahedron Letters p. 2359 - 2362 (1987)

Update date:2022-09-26

Topics:

Authors:

Laurent, E.

Marquet, B.

Tardivel, R.

Thiebault, H.

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Article abstract of DOI:10.1016/S0040-4039(00)96124-0

By anodic oxidation in CH3CN/Et3N, 3HF benzylic ketones, ester and nitrile yield specifically corresponding monofluoro or difluoro compounds.The reaction proceeds through an α-carbonyl or an α-cyano carbocation.

Full text of DOI:10.1016/S0040-4039(00)96124-0

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