STEREOCHEMICAL FEATURES OF CYCLOADDITION OF HETEROAROMATIC N-YLIDES. SELECTIVE PARTICIPATION OF THE ANTI AND SYN YLIDES

DOI: 10.1246/cl.1985.355

Source and publish data:

Chemistry Letters p. 355 - 358 (1985)

Update date:2022-08-04

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Authors:

Tsuge, Otohiko

Kanemasa, Shuji

Takenaka, Shigeori

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Article abstract of DOI:10.1246/cl.1985.355

In the cycloaddition of heteroaromatic N-ylides to symmetrically substituted trans olefins, the anti ylide exclusively participates if the ylide is carbonyl-stabilized, while the syn ylide does if it has a substituent of non-carbonyl type.The cycloadducts

Full text of DOI:10.1246/cl.1985.355

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