Tetrahedron p. 617 - 620 (1985)
Update date:2022-08-04
Topics:
Citterio, Attilio
Gentile, Anna
Minisci, Francesco
Serravalle, Marco
Ventura, Susanna
The homolytic decomposition of hydroxylamine-O-sulphonic acid in alcoholic solvents was investigated in the presence or absence of protonated heteroaromatic bases and Fe(II) salt.THe addition of the α-hydroxyalkyl radicals to the base and their oxidation by Fe(III) salt to the corresponding alkyl cyanide were competitive processes.A redox chain process involving the amino radical cation NH3+, is suggested and the factors affecting the yields of the homolytic substitution are discussed.
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Doi:10.1016/0022-328X(86)80477-6
(1986)Doi:10.1021/ja00306a046
(1985)Doi:10.1134/S1070428014060256
(2014)Doi:10.1007/BF00574260
(1985)Doi:10.1021/jo00221a039
(1985)Doi:10.1021/jo01150a009
(1950)
