A STEREOSELECTIVE SYNTHESIS OF 1,2-DIOLS FROM α-HYDROXYALDEHYDES

DOI: 10.1016/S0040-4039(00)98430-2

Source and publish data:

Tetrahedron Letters p. 1189 - 1192 (1985)

Update date:2022-08-03

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Authors:

Dolence, E. Kurt

Adamczyk, Maciej

Watt, David S.

Russell, Graeme B.

Horn, Dennis H. S.

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Article abstract of DOI:10.1016/S0040-4039(00)98430-2

The addition of lithium acetylides to (20R)-20-hydroxypregnane-22-carboxaldehydes in the absence and in the presence of BF3 afforded predominantly 20R,22R- or 20R,22S-diols, respectively, characteristic of ecdysones.

Full text of DOI:10.1016/S0040-4039(00)98430-2

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