Organometallics p. 1891 - 1893 (1985)
Update date:2022-08-04
Topics:
Fackler Jr., John P.
Trzcinska-Bancroft, Barbara
The first example of the spontaneous isomerization of a metal-metal bonded gold(II) ylide dimer to its mixed-valence Au(III)/Au(I) isomer is reported. This isomerization occurs in nitromethane and other weakly protonic solvents, such as acetone. The X-ray structure of the mixed-valence species shows the presence of a 3.184 (1) ? Au(III)/Au(I) distance.
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Doi:10.1016/j.tetasy.2016.08.014
(2016)Doi:10.1046/j.1532-5415.2002.50036.x
(1956)Doi:10.1055/s-1985-31199
(1985)Doi:10.1016/S0040-4020(97)00789-8
(1997)Doi:10.1007/BF00714941
(1985)Doi:10.1021/jm00149a009
(1985)
