REVERSIBLE ALKIN-ADDITION AN RP-VERBRUECKTE CARBONYLEISEN-CLUSTER

DOI: 10.1016/0022-328X(86)80477-6

Source and publish data:

Journal of Organometallic Chemistry p. 237 - 254 (1986)

Update date:2022-08-04

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Authors:

Knoll, Konrad

Huttner, Gottfried

Zsolnai, Laszlo

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Article abstract of DOI:10.1016/0022-328X(86)80477-6

The clusters (μ₃-RP)2Fe3(CO)9 (1) photochemically add alkines R'CCR' across their bridging phosphorus centers to yield (μ₃-η⁴-RPCR'=CR'PR)Fe3(CO)9 (2).Thermal activation of 2 opens two different reaction channels

Full text of DOI:10.1016/0022-328X(86)80477-6

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