Journal of Organic Chemistry p. 3423 - 3425 (1985)
Update date:2022-08-03
Topics:
Russell, Glen A.
Guo, Deliang
Khanna, Rajive K.
Pyridines or N,N,N',N'-tetramethyl-p-phenylenediamine will undergo a photostimulated free radical chain reaction with alkylmercury halides or carboxylates, yielding ring alkylated substitution products.Alkene mercuration products (R1CH(Y)CH(R2)HgX with Y=HO, RO, CH3CONH; X=Cl, CH3CO2, CF3CO2) can be used without isolation for the alkylation reaction
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