Chemistry of Heterocyclic Compounds p. 264 - 268 (1985)
Update date:2022-08-03
Topics:
Nikolaev, V. A.
Khimich, N. N.
Korobitsyna, I. K.
The principal pathway in the photochemical (λ > 210 nm) transformation of 5-diazo-2,2-dimethyl-4,6-dioxo-1,3-dioxane in an aqueous medium (or in methanol) is splitting out of nitrogen and the Wolff rearrangement to give the stable 2,2-dimethyl-5-oxo-1,3-dioxolane-4-carboxylic acid (or its methyl ester), which undergoes decarboxylation only at temperature above 150 deg C, whereas it undergoes hydrolysis to a hydroxymalonic acid in the presence of trifluoroacetic acid.
View MoreHangzhou Pharma & Chem Co.,Ltd.
Contact:+86-571-87040515
Address:No,139Qingchun Rd
Contact:0086 533 2282832
Address:Zibo，Shandong
Zouping Fuhai Technology Development Co., Ltd.
Contact:+0532-86934525 18660293207
Address:jiuhu town industrial park Zouping County,bingzhou Provincejiuhu town industrial park
Jiangyin Tenghua Import&Export Co.,Ltd.
Contact:+86-510-86263875
Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
Taimai Sanluck Pharmaceutical Co.,Ltd
Contact:86-592-7662921
Address:8D,No.186,Huarong Road,Huli,Xiamen,China
Doi:10.1081/SCC-200061672
(2005)Doi:10.1021/ja011094v
(2001)Doi:10.1021/jo960997h
(1996)Doi:10.1016/S0040-4039(00)95087-1
(1985)Doi:10.1007/BF00515068
(1985)Doi:10.1081/SCC-200054854
(2005)
