Journal of Organic Chemistry p. 4698 - 4702 (1985)
Update date:2022-08-04
Topics:
Murray, Robert W.
Agarwal, Sudhir K.
The olefins 1,4-dibromo-2,3-dimethyl-2-butene, 1-bromo-2,3-dimethyl-2-butene, and 2,3-dimethyl-2-butene were ozonized under a variety of conditions.Ozonolysis of 1,4-dibromo-2,3-dimethyl-2-butene in acetone solvent leads to the unexpected products acetone diperoxide and triperoxide.The results are discussed with respect to questions of concertedness in ozonide formation, the need for activating groups in ozonide formation, and the possible intermediacy of dioxiranes.
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(2013)
