Journal of the Chemical Society. Perkin transactions II p. 811 - 814 (1987)
Update date:2022-09-26
Topics:
da Silva Correa, Carlos M.M.
Oliveira, Maria Augusta B.C.S.
The decomposition of azoisobutyronitrile (AIBN) and t-butyl phenylperacetate in the presence of toluene-p-sulphonyl bromide and iodide were studied; results are explained on the basis of free radical reactions.The relative reactivities of several alkane- and arene-sulphonyl chlorides towards phenyl, benzyl, and trichloromethyl radicals were measured in competition experiments.Results are rationalized on the grounds of a balance between polar effects in the initial and in the transition state.
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