
Journal of Organic Chemistry p. 4252 - 4258 (1984)
Update date:2022-08-03
Topics:
Dauben, William G.
Shapiro, Gideon
The decipiene diterpene nucleus has been synthesized by an intramolecular <2+2> photocycloaddition between an enone and an allene grouping.The process makes use, for the first time, of a stereocontrol element at a remote center in the precursor unit to control the final stereochemistry of the product.A formal total synthesis of (+/-)-trihydroxydecipiadiene has been achieved.
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