A Novel and Efficient Synthesis of the Aspidosperma Alkaloid Ring System: N(a)-Benzyldeethylaspidospermidine

DOI: 10.1021/jo00350a016

Source and publish data:

Journal of Organic Chemistry p. 5517 - 5520 (1985)

Update date:2022-08-02

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Authors:

Gramain, Jean-Claude

Husson, Henri-Philippe

Troin, Yves

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Article abstract of DOI:10.1021/jo00350a016

Nonoxidative photocyclization of the aryl enaminone 3 led to the formation of the hexahydrocarbazol-4-one 4.Alkylation of the anion derived from 4 with iodoacetamide and dehydration gave the tetracyclic enamide 9, which was reduced to the imine 10 with Li

Full text of DOI:10.1021/jo00350a016

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