Total Synthesis of Sericenine

DOI: 10.1021/jo00222a024

Source and publish data:

Journal of Organic Chemistry p. 4326 - 4329 (1985)

Update date:2022-08-04

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Authors:

Honan, Matthew C.

Balasuryia, Asoka

Cresp, Terry M.

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Article abstract of DOI:10.1021/jo00222a024

The total synthesis of the furanogermacrane sesquiterpene sericenine (1) is described.The key intermediate tetralone 6 was synthesized from (3,4-dimethoxyphenyl)acetonitrile (7) in four steps.Carbomethoxylation of 7 gave ester 8 which on conjugate additio

Full text of DOI:10.1021/jo00222a024

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Product name:dimethyl 2-(3,4-dimethoxyphenyl)-2-cyanopentanedioate

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