VOLUMES OF ACTIVATION FOR ANION-DIAZONIUM ION RECOMBINATION

DOI: 10.1016/S0040-4039(00)96280-4

Source and publish data:

Tetrahedron Letters p. 3043 - 3046 (1987)

Update date:2022-07-30

Topics:

Authors:

Isaacs, Neil S.

Najem, Tariq S.

Eldik, Rudi Van

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Article abstract of DOI:10.1016/S0040-4039(00)96280-4

Anion-cation recombination reactions between aryldiazonium ions and anionic nucleophiles have volumes of activation which are small or even negative against expectations of considerably positive values resulting from release of electrostricted solvent.Various interpretations of these results are considered.

Full text of DOI:10.1016/S0040-4039(00)96280-4

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