Synthesis and Photochemistry of 1-Diazo-2-cyclopentene and 2-Diazobicyclohepta-3,6-diene

DOI: 10.1021/jo00383a008

Source and publish data:

Journal of Organic Chemistry p. 1218 - 1221 (1987)

Update date:2022-08-04

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Authors:

Chapman, Orville L.

Abelt, Christopher J.

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Article abstract of DOI:10.1021/jo00383a008

A potentially general route to cyclic α,β-unsaturated diazo compounds via enone tosylhydrazones is described.The unsaturated tosylhydrazone is generated by sulfoxide elimination.Syntheses of 2-diazobicyclo<3.2.0>hepta-3,6-diene and 1-diazo-2-cyclopentene

Full text of DOI:10.1021/jo00383a008

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