EFFECTS OF HETEROATOM SUBSTITUENTS ON THE PROPERTIES OF 1,2-DIOXETANES

DOI: 10.1016/S0040-4039(00)98147-4

Source and publish data:

Tetrahedron Letters p. 3183 - 3186 (1985)

Update date:2022-08-05

Topics:

Authors:

Handley, Richard S.

Stern, Alan J.

Schaap, A. Paul

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Article abstract of DOI:10.1016/S0040-4039(00)98147-4

Nitrogen and sulfur-substituted dioxetanes exhibit dramatically lower activation energies for decomposition compared to the corresponding oxygen-bearing dioxetane.A mechanism involving intramolecular electron-transfer processes is proposed for the cleavage of these unstable dioxetanes.

Full text of DOI:10.1016/S0040-4039(00)98147-4

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