Photoreactions of α,β-Unsaturated γ,δ-Epoxy Nitriles with Amines. The Novel Photoadditions of Tertiary Amines to the α-Position of the Nitriles

DOI: 10.1039/c39940002465

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Journal of the Chemical Society. Chemical communications p. 2465 - 2466 (1994)

Update date:2022-08-05

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Authors:

Ishii, Keitaro

Kotera, Masashi

Sakamoto, Masanori

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Article abstract of DOI:10.1039/c39940002465

Direct irradiation of α,β-unsaturated γ,δ-epoxy nitriles (e.g. 1) and tertiary amines gives rise to a novel 1:1 α-addition and subsequent retro-Michael reaction leading to α-alkylidenenitriles (e.g. 2).

Full text of DOI:10.1039/c39940002465

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