TOTAL SYNTHESIS OF (+/-)-PODOPHYLLOTOXIN AND (+/-)-EPIPODOPHYLLOTOXIN.

DOI: 10.1016/S0040-4039(00)89274-6

Source and publish data:

Tetrahedron Letters p. 3871 - 3874 (1985)

Update date:2022-08-04

Topics:

Authors:

Eycken, J. Van der

Clercq, P. De

Vandewalle, M.

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Article abstract of DOI:10.1016/S0040-4039(00)89274-6

A novel approach to (+/-)-epipodophyllotoxin (2) and hence also (+/-)-podophyllotoxin (1) is described, involving as a key-step the stereoselective ring closure of the TMS-ester derived from 14a to the tetralin derivative 15 with mesyl chloride.

Full text of DOI:10.1016/S0040-4039(00)89274-6

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