Journal of Organic Chemistry p. 179 - 183 (1986)
Update date:2022-08-03
Topics:
Dhawan, Balram
Redmore, Derek
Treatment of diaryl ethyl phosphates 8 with lithium diisopropylamide in tetrahydrofuran yields ethyl bis(2-hydroxyaryl)phosphinates 9.The reaction involves the double migration of phophorus from O-->C and is probably intramolecular.These phosphinate esters 9 on treatment with trimethylsilyl chloride and sodium iodide in acetonitrile undergo transesterification to give trimethylsilyl esters that yield the corresponding phosphinic acids 15 on treatment with water.
View MoreContact:86-532-68629711 13780605697
Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Contact:0086-27-83607103/83642615
Address:No.498, Jianshe Ave, Wuhan, China
Zhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd
Contact:+86 411 84674606
Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China
Contact:0086 371 65711996
Address:Jalan 4/3, Kawasan Perindustrian Serendah, 48000 Rawang,
Zhangjiagang Jianing Import & Export Co.,Ltd.
Contact:086-512-55379012 13913607595
Address:NO.1 Guotai North Road Zhangjiagang Economic Development Zone,215600,Jiangsu,China
Doi:10.1055/s-1972-21959
(1972)Doi:10.1021/cs4004968
(2013)Doi:10.1016/j.tet.2016.01.006
(2016)Doi:10.1039/jr9410000337
(1941)Doi:10.1021/ol030035e
(2003)Doi:10.1016/j.tetasy.2005.02.035
(2005)
