Journal of Organic Chemistry p. 320 - 326 (1986)
Update date:2022-08-03
Topics:
Krespan, Carl G.
Smart, Bruce E.
Fluorocarbanions generated by the addition of an anion to a fluoro olefin can be trapped by fluoro esters, thereby providing a versatile, one-step synthesis of functionalized fluoro ketones.The most efficient anions include CN-, N3-, C6H5O-, RO-, and RS-.The reaction has been extended in one case to prepare a sulfinate ester.
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