Pseudo-Sugars. XIV. Synthesis of Sweet-Tasting Pseudo-β-DL-fructopyranose

DOI: 10.1246/bcsj.59.819

Source and publish data:

Bulletin of the Chemical Society of Japan p. 819 - 822 (1986)

Update date:2022-09-26

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Authors:

Suami, Tetsuo

Ogawa, Seiichiro

Takata, Makoto

Yasuda,Kuninobu

Takei, Kiyoshi

Suga, Atsuo

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Article abstract of DOI:10.1246/bcsj.59.819

Pseudo-β-DL-fructopyranose was synthesized from DL-1,2-di-O-acetyl-(1,3/2)-3-5-cyclohexene-1,2-diol by a six steps reaction: Dehydrobromination, epoxidation, acetolysis, reduction, and deacetylation, in overall yield of 4.8percent.Pseudo-β-DL-fructopyrano

Full text of DOI:10.1246/bcsj.59.819

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Product name:DL-2,3-di-O-acetyl-1,7-anhydro-(1,2/3)-1-C-hydroxymethyl-4-cyclohexene-1,2,3-triol

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