Transition-metal Periodato Complexes. Their Preparations and Properties as Catalytic Oxidants, and X-Ray Crystal Structure of Na4K2>KOH15H2O

DOI: 10.1039/DT9920003489

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Journal of the Chemical Society, Dalton Transactions p. 3489 - 3496 (1992)

Update date:2022-08-30

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Authors:

Dengel, Andrew C.

El-Hendawy, Ahmed M.

Griffith, William P.

Mostafa, Sahar I.

Williams, David J.

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Article abstract of DOI:10.1039/DT9920003489

The preparations and properties as oxidants for alcohols, aldehydes and activated primary alkyl halides of 2>(5-) (M = Cu, Ag or Au), 2>(6-) (M = Ni, Pd or Pt), trans-2>(6-) (M = Ru or Os) and (5-) (M = Mo or W) are reported.The X-ray crystal structure of Na4K2>*KOH*15H2O shows the gold atom to be square planar with coordination by two bidentate (4-) ligands; the 2>(5-) units are linked by NaO6 octahedra to form polymeric chains which are cross-linked by potassium ions.

Full text of DOI:10.1039/DT9920003489

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Article Doi

Transition-metal Periodato Complexes. Their Preparations and Properties as Catalytic Oxidants, and X-Ray Crystal Structure of Na4K2>*KOH*15H2O

DOI: 10.1039/DT9920003489

Source and publish data: