Journal of Organic Chemistry p. 3493 - 3496 (1991)
Update date:2022-08-11
Topics:
Roth, Gregory P.
Fuller, Carl E.
A new and efficient electrophilic partner for palladium(0)-catalyzed cross coupling is reported.Aryl fluorosulfonates are readily prepared in high yield by treatment of the appropriate phenol with fluorosulfonate anhydride.The palladium-catalyzed coupling reactions of these fluorosulfonates with vinyl- and aryltin reagents, as well as organozinc chlorides, takes place under mild conditions in a regio- and stereoselective manner.
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