Thiol-Olefin Cooxidation (TOCO) Reaction. 8. Solvent Effects in the Oxidation of Some Thiols with Molecular Oxygen

DOI: 10.1021/jo00385a015

Source and publish data:

Journal of Organic Chemistry p. 1725 - 1728 (1987)

Update date:2022-08-11

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Authors:

D'Souza, Valerian T.

Iyer, Vaidyanath K.

Szmant, H. Harry

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Article abstract of DOI:10.1021/jo00385a015

The rates of the noncatalytic oxidation of various thiols by molecular oxygen are a function of the chemical environment of the thiol.A relationship between the chemical shifts of the sulfhydryl proton and the rate of oxidation of the given thiol is demonstrated and discussed.

Full text of DOI:10.1021/jo00385a015

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