Solid-phase oxidation of organic compounds with benzyltriphenylphosphonium dichromate

Article abstract of DOI:10.1080/10426500008045240

Benzyltriphenylphosphonium dichromate could be used for oxidation of organic compounds such as alcohols, thiols and sulfides to the corresponding carbonyl, disulfide and sulfoxide derivatives under solid-phase conditions. This reagent is very easily prepared from an aqueous solution of benzyltriphenylphosphonium chloride with CrO₃ in 3 N HCl at room temperature. The reagent, is a stable orange powder, which may be stored for month without loss of its activity.

Full text of DOI:10.1080/10426500008045240

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Phosphorus, Sulfur, and Silicon
and the Related Elements
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SOLID-PHASE OXIDATION OF
ORGANIC COMPOUNDS WITH
BENZYLTRIPHENYLPHOSPHONIUM
DICHROMATE
a
b
A. R. Hajipour & Iraj Mohammadpoor-baltork
a
Pharmaceutical Research Laboratory, College
of Chemistry , Isfahan University of Technology ,
Isfahan, 84156 IR, IRAN
b
Department of Chemistry , Isfahan University ,
Isfahan, 81 744, IRAN
Published online: 27 Oct 2006.
To cite this article: A. R. Hajipour & Iraj Mohammadpoor-baltork (2000) SOLID-
PHASE OXIDATION OF ORGANIC COMPOUNDS WITH BENZYLTRIPHENYLPHOSPHONIUM
DICHROMATE, Phosphorus, Sulfur, and Silicon and the Related Elements, 164:1,
145-151, DOI: 10.1080/10426500008045240
To link to this article: http://dx.doi.org/10.1080/10426500008045240
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