Porphyrinatoiron-catalyzed Reduction of Styrene with Sodium Borohydride: Proposed ?-Alkyliron(III) Complex as an Intermediate

DOI: 10.1039/c39910001728

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1728 - 1729 (1991)

Update date:2022-08-17

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Authors:

Kano, Koji

Takeuchi, Masayuki

Hashimoto, Shizunobu

Yoshida, Zen-ichi

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Article abstract of DOI:10.1039/c39910001728

5,10,15,20-Tetrakis(para-substituted phenyl)porphyrinatoiron(III) chloride complexes catalyse the reduction of styrene with NaBH4 to ethylbenzene and 2,3-diphenylbutane and the precursor is assumed to be the ?-alkyl complex (Xtpp)Fe^III-PhCHMe.

Full text of DOI:10.1039/c39910001728

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