SILVER-CATALYZED REDUCTIVE DEHALOGENATION OF 1,1-DIBROMOCYCLOPROPANES

DOI: 10.1246/cl.1983.1877

Source and publish data:

Chemistry Letters p. 1877 - 1878 (1983)

Update date:2022-08-17

Topics:

Authors:

Shimizu, Nobujiro

Watanabe, Kenji

Tsuno, Yuho

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Article abstract of DOI:10.1246/cl.1983.1877

1,1-Dibromocyclopropanes underwent rapid reduction to the corresponding monobromides in high yields on treating with LiAlH4 - 1 molpercent silver perchlorate in THF, presumably via a silver-catalyzed radical chain mechanism.

Full text of DOI:10.1246/cl.1983.1877

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