PALLADIUM CATALYZED HYDROSTANNATION OF ALKYNES AND PALLADIUM-CATALYSED HYDROSTANNOLYSIS OF PROPARGYL OR PROPARGYLOXYCARBONYL DERIVATIVES OF VARIOUS FUNCTIONAL GROUPS

DOI: 10.1016/S0040-4039(00)80165-3

Source and publish data:

Tetrahedron Letters p. 619 - 622 (1988)

Update date:2022-08-31

Topics:

Authors:

Zhang, H. X.

Guibe, F.

Balavoine, G.

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Article abstract of DOI:10.1016/S0040-4039(00)80165-3

PdCl2(PPh3) catalyses, under very mild conditions, the cis-hydrostannation of acetylenic compounds by tributyltin hydride and the hydrostannolytic clevage of propargyl carboxylates, phosphates, carbonates and carbamates.The latter reaction should find use in protective group chemistry.

Full text of DOI:10.1016/S0040-4039(00)80165-3

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