Journal of Organometallic Chemistry p. 233 - 236 (1994)
Update date:2022-08-17
Topics:
Tanase, Tomoaki
Mochizuki, Hidetoshi
Sato, Ryoichi
Yamamoto, Yasuhiro
(η5-In)Ru(η1-C<*>CPh)(PPh3)2 (In=indenyl) treated with nitric oxide (1 atm) in the presence of NaClO4 gave <(η5-In)Ru(CO)(PPh3)2>ClO4*0.5CH2Cl2 and benzonitrile (PhC<*>N) in good yields, through a novel metathesis reaction between ?-acetylide and NO. (η6-C6Me6)Ru(η1-C<*>CPh)(PPh3)Cl also readily underwent the metathesis reaction with NO to afford benzonitrile. Key words: Ruthenium; Nitrosyl; Indenyl; Metathesis
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