Unexpected Staudinger Reaction of α-Azidophenylacetonitrile and Triphenylphosphine: Synthesis and Crystal Structure of Aminotriphenylphosphonium Salt of Phenylmalononitrile

DOI: 10.1039/c39950001387

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1387 - 1390 (1995)

Update date:2022-08-11

Topics:

Authors:

Molina, Pedro

Lopez-Leonardo, Carmen

Llamas-Botia, Javier

Foces-Foces, Concepcion

Fernandez-Castano, Cristina

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39950001387

Staudinger reaction of α-azidophenylacetonitrile with triphenylphosphine in 1:2 molar ratio provides the triphenylphosphinazine derived from α-diazophenylacetonitrile, whereas in 2:1 molar ratio the final product is found to be the aminotriphenylphosphonium salt of phenylmalononitrile; X-ray structure analysis of this salt indicates that the anion and cation interact with one another via hydrogen bonding.

Full text of DOI:10.1039/c39950001387

View Online / Journal Homepage / Table of Contents for this issue

View Online

Products guided by the article

Product name:Benzonitrile

Cas No:100-47-0

R&D Labs maybe for 100-47-0

WUXI HONOR SHINE CHEMICAL CO.,LTD

Contact:+86-510-83593312

Address:No.1699 Huishan avenue,Huishan district,Wuxi ,Jiangsu,China,214177.(Wuxi Huishan Ecomonic Develop Zone )
Anhui Eapearl Chemical Co., Ltd.

Contact:86-562-5858458

Address:358 South Huaihe Road
Tangshan Wisdom Trading Co.,Ltd

Contact:86 315 2222979

Address:No.41 BeiXinXi Road, Yangguang building 1-1102 , Tangshan, Hebei, China
EGBERT CORPORATION

Contact:+86 18616952870

Address:Area
Jiaxing Taixin Pharmaceutical Chemical Co., Ltd

Contact:0573-82613601

Address:Chemical Park, Jiaxing, Zhejiang, China

Relevant to this article

Design, synthesis and in vitro cell-free/cell-based biological evaluations of novel ERCC1-XPF inhibitors targeting DNA repair pathway

Doi:10.1016/j.ejmech.2020.112658
(2020)
Palladium (II) complexes chelated by 1-substituted-4-pyridyl-1H-1,2,3-triazole ligands as catalyst precursors for selective ethylene dimerization

Doi:10.1002/aoc.5595
(2020)
Synthesis of 2-methyl-5-(5-phenyl substituted-1,3,4 oxadiazole-2-yl) quinazolin-4-one fluorescent brightening agent: Computational and experimental comparison of photophysical structure

Doi:10.1016/j.molstruc.2019.01.039
(2019)
A copolymer capsule with a magnetic core for hydrophilic or hydrophobic drug delivery via thermo-responsive stimuli or carrier biodegradation

Doi:10.1039/c5ra27839b
(2016)
SYNTHESIS OF 3-ALKYL- AND 3-ARYLPYRIDINES

Doi:10.1007/BF00531338
(1992)
Doi:10.1021/jo00826a051
(1970)

Article Doi